{"search_session":{},"preferences":{"l":"en","queryLanguage":"en"},"patentId":"US_7482451_B2","frontPageModel":{"patentViewModel":{"ref":{"entityRefType":"PATENT","entityRefId":"133-240-385-290-964"},"entityMetadata":{"linkedIds":{"empty":true},"tags":[],"collections":[{"id":10771,"type":"PATENT","title":"University of Southern California - Patent Portfolio","description":"","access":"OPEN_ACCESS","displayAvatar":true,"attested":false,"itemCount":8387,"tags":[],"user":{"id":91044780,"username":"Cambialens","firstName":"","lastName":"","created":"2015-05-04T00:55:26.000Z","displayName":"Cambialens","preferences":"{\"usage\":\"public\",\"beta\":false}","accountType":"PERSONAL","isOauthOnly":false},"notes":[{"id":8241,"type":"COLLECTION","user":{"id":91044780,"username":"Cambialens","firstName":"","lastName":"","created":"2015-05-04T00:55:26.000Z","displayName":"Cambialens","preferences":"{\"usage\":\"public\",\"beta\":false}","accountType":"PERSONAL","isOauthOnly":false},"text":"
M is a metal with an atomic weight of greater than 40,\n
X and Y are each an independently selected from pyrazoles, tetrazoles, thiazoles, furans and pyridines,\n
Z is a group of the formula JR′pR″q \n\nwherein J is hydrogen or a metal or a non-metal, R′ and R″ are independently, alkenyl, heteroaryl, hydroxy, alkoxy, aryloxy, amino, alkylamino, arylamino, sulfido, alkylsulfido, arylsulfido, phophino, alkylphosphino or arylphosphino and p and q are integers between 0 and 2.\n
m and n are integers selected from 1 and 2 wherein the sum of n+m is 3,\n
with the proviso that\n\nis anionic."],"number":1,"annotation":false,"title":false,"claim":true},{"lines":["The compound of claim 1, wherein J is boron."],"number":2,"annotation":false,"title":false,"claim":true},{"lines":["The compound of claim 1 wherein R′ and R″ are selected from the group consisting of alkyls, aryls, and pyrazoles and p and q are each 1."],"number":3,"annotation":false,"title":false,"claim":true},{"lines":["The compound of claim 3 wherein R′ is pyrazole, R″ is a pyrazole and p and q are each 1."],"number":4,"annotation":false,"title":false,"claim":true},{"lines":["The compound of claim 1 wherein X and Y are pyrazoles."],"number":5,"annotation":false,"title":false,"claim":true},{"lines":["The compound of claim 5, wherein Z is hydrogen."],"number":6,"annotation":false,"title":false,"claim":true},{"lines":["The compound of claim 1, wherein the heavy metal is selected from the group consisting of Ir, Pt, Pd, Rh, Re, Os, Tl, Pb, Bi, In, Sn, Sb, Te, Ag, and Au."],"number":7,"annotation":false,"title":false,"claim":true},{"lines":["The compound of claim 6 wherein the heavy metal is Ir."],"number":8,"annotation":false,"title":false,"claim":true},{"lines":["The compound of claim 6 wherein the heavy metal is Pt."],"number":9,"annotation":false,"title":false,"claim":true},{"lines":["The compound of claim 1, having the Formula III:\nwherein each R11 and R12 is independently selected from alkyl, alkenyl, alkynyl, alkylaryl, CN, CF3, CO2R, C(O)R, NR2, NO2, OR, halo, aryl, heteroaryl, substituted aryl, substituted heteroaryl or a heterocyclic group, and additionally, or alternatively, any two adjacent substituted positions together form, independently, a fused 5- to 6-member cyclic group, wherein said cyclic group is cycloalkyl, cycloheteroalkyl, aryl, or heteroaryl, and wherein the fused 5- to 6-member cyclic group cyclic group may be optionally substituted with one or more of alkyl, alkenyl, alkynyl, alkylaryl, CN, CF3, CO2R, C(O)R, NR2, NO2, OR, or halo;\n
each R is independently alkyl, aryl, or heteroaryl; and\n
subscript a and b are independently selected from 0, 1, 2, and 3."],"number":10,"annotation":false,"title":false,"claim":true},{"lines":["The compound of claim 10, having the formula IV:"],"number":11,"annotation":false,"title":false,"claim":true},{"lines":["The compound of claim 1, having the Formula V:\nwherein each R11, R12, R13, and R14 is independently selected alkyl, alkenyl, alkynyl, alkylaryl, CN, CF3, CO2R, C(O)R, NR2, NO2, OR, halo, aryl, heteroaryl, substituted aryl, substituted heteroaryl or a heterocyclic group, and additionally, or alternatively, any two adjacent substituted positions together form, independently, a fused 5- to 6-member cyclic group, wherein said cyclic group is cycloalkyl, cycloheteroalkyl, aryl, or heteroaryl, and wherein the fused 5- to 6-member cyclic group cyclic group may be optionally substituted with one or more of alkyl, alkenyl, alkynyl, alkylaryl, CN, CF3, CO2R, C(O)R, NR2, NO2, OR, or halo;\n
each R is independently alkyl, aryl and heteroarl; and\n
subscript a, b, c, and d are independently selected from 0, 1, 2, and 3."],"number":12,"annotation":false,"title":false,"claim":true}]}},"filters":{"npl":[],"notNpl":[],"applicant":[],"notApplicant":[],"inventor":[],"notInventor":[],"owner":[],"notOwner":[],"tags":[],"dates":[],"types":[],"notTypes":[],"j":[],"notJ":[],"fj":[],"notFj":[],"classIpcr":[],"notClassIpcr":[],"classNat":[],"notClassNat":[],"classCpc":[],"notClassCpc":[],"so":[],"notSo":[],"sat":[]},"sequenceFilters":{"s":"SEQIDNO","d":"ASCENDING","p":0,"n":10,"sp":[],"si":[],"len":[],"t":[],"loc":[]}}