{"search_session":{},"preferences":{"l":"en","queryLanguage":"en"},"patentId":"100-813-635-107-48X","frontPageModel":{"patentViewModel":{"ref":{"entityRefType":"PATENT","entityRefId":"100-813-635-107-48X"},"entityMetadata":{"linkedIds":{"empty":true},"tags":[],"collections":[{"id":10783,"type":"PATENT","title":"Carnegie Mellon University - Patent Portfolio","description":"","access":"OPEN_ACCESS","displayAvatar":true,"attested":false,"itemCount":3541,"tags":[],"user":{"id":91044780,"username":"Cambialens","firstName":"","lastName":"","created":"2015-05-04T00:55:26.000Z","displayName":"Cambialens","preferences":"{\"usage\":\"public\",\"beta\":false}","accountType":"PERSONAL","isOauthOnly":false},"notes":[{"id":8253,"type":"COLLECTION","user":{"id":91044780,"username":"Cambialens","firstName":"","lastName":"","created":"2015-05-04T00:55:26.000Z","displayName":"Cambialens","preferences":"{\"usage\":\"public\",\"beta\":false}","accountType":"PERSONAL","isOauthOnly":false},"text":"
Search Applicants and Owners separately: \"Carnegie Mellon Univ*\";
Select more for logical variants. Add to collection. Select all patents in the collection and expand by simple families. Add to collection. Total patents: 2619
Search Applicants and Owners separately:univ* AND Leipzig. Select more for logical variants. Add to collection. Select all patents in the collection and expand by simple families. Add to collection. Total patents: 1306
Search Applicants and Owners separately: \"Carnegie Mellon Univ*\";
Select more for logical variants. Add to collection. Select all patents in the collection and expand by simple families. Add to collection. Total patents: 2619
Search Applicants and Owners separately:univ* AND Leipzig. Select more for logical variants. Add to collection. Select all patents in the collection and expand by simple families. Add to collection. Total patents: 1306
at least one transition metal catalyst that can participate in a redox reaction; and\n
an initiator comprising one or more redox transferable atoms or groups;\n
wherein the molar ratio of the oxidation states of the transition metal catalyst are adjusted, controlled, and/or maintained by electrochemistry."],"number":1,"annotation":false,"title":false,"claim":true},{"lines":["The polymerization process of claim 1, wherein the polymerization takes place in an electrolysis apparatus comprising at least a cathode and an anode, and\n
wherein electrolysis is controlled by one or more of applied voltage, current, and charge passed, and wherein the electrolysis control is selected to provide a concentration greater than or equal to 0.1% of each oxidation state of the at least one transition metal catalyst based on total transition metal added in the polymerization medium."],"number":2,"annotation":false,"title":false,"claim":true},{"lines":["The polymerization process of claim 2, wherein the rate of polymerization is controlled through the magnitude of the one or more of applied voltage, current, and charge passed applied to the system."],"number":3,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 3, wherein the molar ratio of two oxidation states of the transition metal catalyst at a specific time in the polymerization is determined by the one or more of applied voltage, current, and total charge passed through the polymerization medium and current values."],"number":4,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 1, wherein the polymerization process can be started and stopped by changing the applied voltage or current, or switching the applied voltage or current “on” or “off”, optionally where the applied voltage or current is capable of controlling a reaction exotherm."],"number":5,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 1, wherein the concentration of the at least one transition metal catalyst in the polymerization medium is less than 1000 ppm."],"number":6,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 1, wherein the at least one transition metal catalyst comprises one or more ligands."],"number":7,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 1, wherein the at least one transition metal catalyst complex comprises two different ligands."],"number":8,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 1, wherein the at least one transition metal catalyst comprises two different transition metals."],"number":9,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 7, wherein the voltage applied to the polymerization medium is based on the Em value, as determined by cyclic voltammetry, of the at least one transition metal catalyst and one or more ligands in the polymerization medium."],"number":10,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 7, wherein the voltage applied to the polymerization medium is based on the E1/2 value, as determined by cyclic voltammetry, of the at least one transition metal catalyst, one or more ligands, the monomers, optionally a solvent and optionally an electrolyte in the polymerization medium."],"number":11,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 11, wherein the voltage applied to the polymerization medium is based on the E1/2 value, as determined by cyclic voltammetry, of the at least one transition metal catalyst, the one or more ligands, the monomers, the initiator, the optional solvent and the optional electrolyte in the polymerization medium."],"number":12,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 1, wherein the concentration of the at least one transition metal catalyst in the polymerization medium is reduced by electrodeposition of the at least one transition metal."],"number":13,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 1, wherein a transition metal catalyst complex is formed in-situ directly from a reaction of a solid transition metal deposited on an electrode with one or more ligands in the polymerization medium."],"number":14,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 3, wherein the relative concentration of a higher oxidation state transition metal catalyst and a lower transition metal catalyst are adjusted through the magnitude of the voltage or current applied to the polymerization medium to control the polymerization of radically (co)polymerizable monomers with the at least one transition metal catalyst and one or more ligands."],"number":15,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 1, wherein the polymerization medium is a medium selected from the group consisting of an organic medium, an aqueous medium and a biphasic medium."],"number":16,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 1, wherein electrochemistry selected from applied potential and/or current is adjusted at one or more times during the polymerization process."],"number":17,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 1, wherein the polymerization medium further comprises an electrolyte."],"number":18,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 18, wherein electrochemistry selected from applied voltage and current is selected to retain at least 0.1% concentration of both an activator state of the at least one transition metal catalyst and a deactivator state of the at least one transition metal catalyst in the polymerization medium throughout the time period(s) when an active polymerization is desired."],"number":19,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 18, wherein the electrolyte comprises a same counterion present on a first added transition metal salt that forms the at least one transition metal catalyst."],"number":20,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 18, wherein the electrolyte comprises a different counterion from that present on a first added transition metal salt that forms the at least one transition metal catalyst."],"number":21,"annotation":false,"title":false,"claim":true},{"lines":["The process of claim 21, wherein the electrolyte comprises a quaternary ammonium complex or a triflate."],"number":22,"annotation":false,"title":false,"claim":true}]}},"filters":{"npl":[],"notNpl":[],"applicant":[],"notApplicant":[],"inventor":[],"notInventor":[],"owner":[],"notOwner":[],"tags":[],"dates":[],"types":[],"notTypes":[],"j":[],"notJ":[],"fj":[],"notFj":[],"classIpcr":[],"notClassIpcr":[],"classNat":[],"notClassNat":[],"classCpc":[],"notClassCpc":[],"so":[],"notSo":[],"sat":[]},"sequenceFilters":{"s":"SEQIDNO","d":"ASCENDING","p":0,"n":10,"sp":[],"si":[],"len":[],"t":[],"loc":[]}}